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Search in Samsung Galaxy S6 edge
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Choosing a default email account for my mobile phone
If you've set up more than one email account on your mobile phone, you need to select a default email account. When you write email, they'll automatically be sent from your default email account.
Tap Apps.
Tap Email.
Tap MORE.
Tap Settings.
Tap MORE.
Tap Set default account.
Tap the required email account.
Tap DONE.
Tap the Home key to return to the home screen.